Provider Grantová agentura České republiky
GA 104/09/0621 2009-2011
Proposer prof. Ing. David Sedmidubský Dr., VŠCHT
Co-proposer Ing. Dr. Jiří Hejtmánek CSc., FU AV ČR, v.v.i.
doc. RNDr. Anna Macková Ph.D., UJF AV ČR, v.v.i.
Title ZnO-based magnetic semiconductors
Název Magnetické polovodiče na bázi ZnO

The semiconductors based on ZnO doped by magnetic impurities belong to a new class of advanced materials, dilute magnetic semiconductors, which have recently received much experimental and theoretical attention as a suitable spin source for spintronic applications. Some of the highly doped wide band gap materials like (Zn,Mn)O reveal a ferromagnetic like behavior near and above room temperature, which is considered as a major criterium for spintronic applications. The present project focuses on material and technological aspects of transition metal (TM) and rare earth (RE) doped ZnO thin films fabricated by metalorganic chemical vapor deposition (MOCVD) technique. The TM and RE elements will be incorporated either by ion implantation followed by annealing or by in-situ MOCVD using MO precursors as TM sources. The corresponding bulk materials will be prepared by ceramic route or as single crystals. The sythetized materials will be chemically and structurally characterized and their magnetic and electric transport properties will be thoroughly examined. The thermodynamic and electronic structure calculations will be used as auxiliary tools to model the MOCVD process and to interpret the physical properties.